Joan Of Arc
One Knights costume
Dress your daughter up in the knights costume, and use the charcoal to give the costume and her face that freshly roasted look. Use the scissors to chop off all her hair - or better yet, have her do it! That rough worn look you get from cutting off your own locks really adds to the whole warrior in God's army vibe.
Dress your daughter in the blouse and skirt, put on the apron, and then lightly apply the makeup on her face until she has that healthy green glow. The perfect costume to teach her a lesson about women's achievements in science and why it's not the best idea to watch your food cook in the microwave.
Ill fitting tweed coat
Some dopey looking hat
Long string of fake pearls
Dress your daughter like she doesn't care what she looks like, because who can care about things like that when there are coal miners to save, or whatever it was that Eleanor Roosevelt did. Alternatively, if you don't feel like explaining what the Great Depression was (better sooner than later!) or what a "beard" is, this same outfit can also be passed off as the classic "Female Hobo".